I've got no clue if I clicked on some hotkey or deactivated the viewport to update but my materials will not update to save my life. If someone has ran into a similar issue please let me know. I've tried examining a previous file where my materials are updating but can't find a solution.
Update 3 Rearranged the Hotkeys. Orientation completed. Modeling changed a bit. Content should be complete now. Next Update would be to Detail the overall Blockout. Comments and Critique almost appreciated.