Hi guys, I just thought I would mention my Maya Python autorig tutorial. It's basically a video tutorial series that you can download and learn how to script in python from. I am using Maya to create a python script that builds a creature rig in one click. If you would like to learn how to automate processes in Maya then…
Ya I know that there moving more to Python, but don't you have to load Mel script commands in to the Python engine when your in Maya? Also don't you need to understand Mel script syntax to get the most out of Python?
Definitely an awesome book. Borrowed it from the library and think work has it in the bookshelf somewhere. Another awesome book if you're getting into Maya scripting [ame="http://www.amazon.com/Maya-Python-Games-Film-Reference/dp/0123785782"]Maya Python for Games and Film: A Complete Reference for Maya Python and the Maya…
I'd go for python script instead. Same commands available but you gain a lot more general python functionality. Such as handling strings, lists, etc. Here's a good guide for getting started. http://www.chadvernon.com/blog/resources/python-scripting-for-maya-artists/