Sorry I should have been clearer, I want to use shortcuts like shif-alt-m/c/n to set layers to mutiply/colour/normal mode as well as just 1 to 0 for setting values, at the moment its virtually usless for me because randomly it will work on the layer or the brush
If you have a brush active, it should always do it for the brush, if you want it to be done on the layer instead, what I do is switch to selection mode quickly (v), then back to the brush.
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but here's some handy shortcuts.
new layer is: Ctrl-Shift-N
fill with foreground: alt-backspace
fill dialog: shift-backspace
brush tool: b