Many people me included love to create 3d concepts in mudbox because it's fast and powerful.
But since you can paint in mudbox, there is nothing stopping you from using it as a painting tool like photoshop or painter especially since in version 2011 when you got all these sweet new painting tools
http://area.autodesk.com/tutorials/drawing_in_mudbox-1
access to area members only!
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if you havnt checked em out yet here are a few links.
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