I tried to use colors that were as different from each other as possible to avoid confusion, so I have black, white, red, green, blue, cyan, magenta, and yellow, however I cannot seem to select cyan or magenta to assign a material to them. Am I doing something wrong here?
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Alternatively, you can take those colors and turn them into a standard mask. Page 16 of my DDO tutorial should clarify: https://www.artstation.com/artwork/oBWR4