haiddasalami: First off wicked picture :) Secondly thanks a lot! I figured the way to do it, if at all would be scripting, but unfortunately I don't know anything about scripting. But yes please let me know if you figure it out, that would be amazing. Cheers!
Ok so just tried it and the only way was to add it to your swatches. Might be something scriptable just need to look into it. Will try and get back to you by tomorrow if I get anything. Thinking something like a script that runs as Photoshop opens, and basically stores the last 5 colors you sampled and hitting a hotkey…